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<p class="MsoNormal" style="line-height:115%"><span style="line-height: 115%; font-size: 14px;" class=""><font face="Times New Roman" class="">Dear all,
<o:p class=""></o:p></font></span></p>
<p class="MsoNormal" style="line-height:115%"><span style="line-height: 115%; font-size: 14px;" class=""><font face="Times New Roman" class="">Please join us this Thursday for our speaker, Stefanie Helmrich from UC Merced.
<o:p class=""></o:p></font></span></p>
<p class="MsoNormal" align="center" style="text-align:center;line-height:115%"><b class=""><span style="line-height: 115%; font-size: 14px;" class=""><font face="Times New Roman" class=""> </font></span></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><b class=""><font face="Times New Roman" style="font-size: 14px;" class="">Stefanie Helmrich<o:p class=""></o:p></font></b></p>
<p class="MsoNormal" align="center" style="text-align:center"><font face="Times New Roman" style="font-size: 14px;" class="">Environmental systems, UC Merced<o:p class=""></o:p></font></p>
<p class="MsoNormal" align="center" style="text-align:center"><font face="Times New Roman" style="font-size: 14px;" class=""> </font></p>
<p class="MsoNormal" style="text-align: center;"><b class=""><font face="Times New Roman" style="font-size: 14px;" class="">Simulating methylmercury production at the sediment-water interface to improve the water quality in the San Francisco Bay-Delta<o:p class=""></o:p></font></b></p>
<p class="MsoNormal"><b class=""><font face="Times New Roman" style="font-size: 14px;" class=""> </font></b><b style="font-size: 14px; font-family: 'Times New Roman'; text-indent: 0in;" class="">Abstract</b><span style="font-size: 14px; font-family: 'Times New Roman'; text-indent: 0in; line-height: 115%;" class="">:
Mercury (Hg) in the environment poses a significant threat to human and ecological health, and is a major contaminant of concern for water quality in California. Methylmercury (MeHg) is the most toxic form of Hg and bioaccumulates in fish and higher organisms.
The San Francisco Bay-Delta received significant amounts of inorganic Hg from the Sierra Nevada foothills due to historic gold mining and anoxic sediments in wetlands in the Delta are hotspots for bacterially driven MeHg production. Environmental conditions
that influence the net methylation of Hg are known, but quantification of water-column concentrations of MeHg is still difficult because of the high cost of collecting data over detailed spatial and temporal scales. However, quantification of MeHg concentrations
is important to plan mitigation and remediation measures. Computer simulations can provide a tool to predict Hg and MeHg concentrations over a range of hydrologic conditions and improve understanding of hydrogeochemical and biological processes controlling
Hg and MeHg transport and fate. As such, I am developing a mechanism-based reactive-transport model to simulate the mercury cycle at the sediment-water interface. As a first step, I am investigating how to utilize incubation experiments with isotopically labeled
tracers to parameterize (de)methylation reactions in the model. A considerable number of incubation experiments has been carried out in the last two decades. However, the assumptions made in calculating (de)methylation rate constant, and the conditions of
the incubation experiments differ between studies. I am assessing the suitability of the reported rate constants for use in a generalized kinetic model and I will assess the selected rate constants by comparing simulated MeHg concentrations with in incubation
experiments measured MeHg concentrations. It is important to note that the kinetic rates and the corresponding rate constants are empirical in nature, however, the thermodynamic framework is not empirical. The model development will yield new insights and
the mechanistic model can be applied to sites with the same environmental conditions to simulate MeHg concentrations at the sediment-water interface.</span></p>
<p class="MsoNormal"><font face="Times New Roman" style="font-size: 14px;" class=""><b class="">Biography</b>: Stefanie is a second year Ph.D. student and her research aim is to develop and scale up a biogeochemical reaction-transport model for simulating the
fate of mercury. Before Stefanie came to UC Merced, she graduated with a Master of Science in Water Management from Technical University of Dresden in Germany and she did an internship at the Lawrence Berkeley National Lab. Her master thesis focused on two-dimensional
surface-runoff simulations coupled to a channel network model to predict flooding in urban areas. As an intern at the Berkeley Lab Stefanie used SJRWARMF to simulate the fate of mercury on the watershed scale.
<o:p class=""></o:p></font></p>
<p class="MsoNormal"><font face="Times New Roman" style="font-size: 14px;" class=""> </font></p>
<p class="MsoNormal"><font face="Times New Roman" style="font-size: 14px;" class="">When: Nov. 2<sup class="">nd</sup>,<sup class="">
</sup>Thursday, 12pm – 1pm<o:p class=""></o:p></font></p>
<p class="MsoNormal"><font face="Times New Roman" style="font-size: 14px;" class="">Where: SE2-302
<o:p class=""></o:p></font></p>
<p class="MsoNormal"><font face="Times New Roman" style="font-size: 14px;" class=""> </font></p>
<p class="MsoNormal"><font face="Times New Roman" style="font-size: 14px;" class="">Coffee will be provided and please bring your own mugs.
<o:p class=""></o:p></font></p>
<p class="MsoNormal"><font face="Times New Roman" style="font-size: 14px;" class="">We look forward to seeing you,<o:p class=""></o:p></font></p>
<p class="MsoNormal"><font face="Times New Roman" style="font-size: 14px;" class=""> </font></p>
<p class="MsoNormal"><font face="Times New Roman" style="font-size: 14px;" class="">Organizers for 2017-18: Nate Bogie and Lixia Jin<o:p class=""></o:p></font></p>
<p class="MsoNormal"><font face="Times New Roman" class=""><span style="font-size: 14px;" class="">Faculty coordinator: Asmeret Asefaw Berhe</span><span style="font-size: 9pt;" class=""><o:p class=""></o:p></span></font></p>
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